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In a cocktail shaker, combine the vodka, lemon juice, simple syrup and ice cubes. Shake lightly to mix.
If desired, dip the rims of the shot glasses in lemon juice and then in the loose sugar to coat them.
Divide the mixture between 4-5 shot glasses and top with a lemon wedge.
Serving: 1g | Calories: 101kcal | Carbohydrates: 10g | Sodium: 6mg | Fiber: 1g | Sugar: 8g